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کنکور زیست و شیمی تبریز - انرژی شبکه، نقطه ذوب و جوش
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- انرژی شبکه مقدار انرژی آزاد شده به هنگام تشکیل یک مول جامد یونی از یونهایی گازی سازنده آن است.
- انرژی شبکه با بار یون نسبت مستقیم و با شعاع آن نسبت معکوس دارد.
- اگر در دو ترکیب بار یونهای مشابه مساوی باشد، هر چه شعاع کمتر باشد انرژی شبکه بیشتر است.
- هر چقدر چگالی بار (نسبت بار به شعاع) بیشتر باشد انرژی شبکه افزایش می یابد.
- به طور کلی هر چه انرژی شبکه بیشتر باشد نقطه ذوب و جوش ترکیب بالاتر است اما در برخی موارد استثناهایی دیده می شود. پایداری شبکه بلور عاملی است که می تواند این قاعده را نقض کند. مثلا انرژی شبکه Al2O3 بیشتر از MgO است اما نقطه ذوب و جوش آن از MgO کمتر است.
- مقایسه انرِژی شبکه چند ترکیب یونی که تاثیر بار و شعاع را بهتر متوجه شوید

AlF3 > MgF2 > NaF
Al2O3> MgF2
Fe2O3 > FeO > FeCl2
MgO > MgF2 > Na2O

Al2O3 > MgO > Na2O

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